of Zn +2 ions as well as S-2 ions is 4. For constructive interference 2 d Sinq must be equal to nl The radius ratio of 0.524 for NaCl suggest an octahedral void.Imperfection in Solids Table of contents...Imperfections in solids: Defects in Crystals Table...Ionic compounds of the type AB have three types of crystalline structures. No of sodium ions = 12 (at edge centres) × 1/4 + 1 (at body centre) × 1= 4 Electrical Properties Table of contents... Other common examples of this type of structure are CsBr, CsI, TlCl, TlBr General Characteristics of Solid State Table of...Packing Efficiency Table of contents Packing...The unit cell of sodium chloride has 4 sodium and 4 chloride ions as calculated below Amorphous and Crystalline Solids Table of contents...Classification of Crystalline Solids Table of...Packing Fractions Table of Content Simple Cubic...Solved Problems Question: 1 It can be seen now...So, path difference = 2d Sinθ Or, nγ = 2 d Sinθ From the knowledge of close packed structures and the voids developed there in, we can have an idea about the structures of simple ionic compounds. Related Structure: Wurtzite (ZnS) Also, this structure has the cations (zinc ions) occupying one of the two types of tetrahedral holes present in the structure, but it has two asymmetric units in its unit cell.Zinc blende and wurtzite are two forms of zinc sulfide. The ionic radius of the zinc(II) ion is 0.74 Å and that of the sulfide ion is 1.70 Å. These are characterized by a 1:1 stoichiometric ratio of Zinc to Sulfur. It is a thermodynamically more favoured structure than the other form of zinc sulfide. Notice how only half of the tetrahedral sites are occupied.Fig. The key difference between zinc blende and wurtzite is that zinc blend is cubic, whereas wurtzite has a hexagonal structure.Madhu is a graduate in Biological Sciences with BSc (Honours) Degree and currently persuing a Masters Degree in Industrial and Environmental Chemistry. Since zinc blend is more thermodynamically stable than wurtzite, the wurtzite form tends to convert into zinc blend slowly. However, this structure has low thermodynamic stability; thus, it slowly converts into a zinc blende structure. zinc). Structural and electronic properties characterization results show that the crystallographic structure of CdSe films, deposited by chemical bath synth… (L:42) Structure of ionic solids/structure of ZnS/zinc blende and wurtzite structure This type of superlattice had the potential to produce the “anomalous photovoltaic effect” [2, 3] and thus may be applied in the solar energy conversion and utilization.
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